1Label the seats $1, \ldots, 10$ around the circle; we pair each person with a neighbor, covering everyone with $5$ non-overlapping adjacent edges.
2A circle of $2n$ vertices has exactly $2$ such 'all-adjacent' perfect matchings: the edges $\{1,2\},\{3,4\},\ldots$ or the shifted edges $\{2,3\},\{4,5\},\ldots,\{10,1\}$.
3To see why, fix person $1$: they pair with either neighbor ($2$ choices), and that choice forces every subsequent pairing all the way around the cycle with no freedom left.
4So there are exactly $2$ matchings.